Structural and phase characteristics of the diamond/matrix interfacial zone in high-resistant diamond composites

The structural-phase state of the contact zone and the factors that influence on the strength of diamond retention in the diamond carbide composites were determined. Composites were obtained by the new hybrid technology that eliminates the reheating of the metalized coating. The elaborated technology combines the thermal diffusion metallization of a diamond and the sintering by the scheme of self-dosed impregnation in a one-stage technological cycle. By the methods of electron microscopy, X-ray diffraction analysis, and Raman spectroscopy the structural and phase characteristics of the interphase boundary were investigated. The improvement of chemical and mechanical adhesion between the diamond and carbide matrix was obtained. It was shown that the specific productivity of the samples with a metalized diamond component is 39% higher than those without metallization.     

Separation and purification of scandium: From industry to medicine

Scandium and its compounds are used in many modern industrial fields due to its unique chemical and physical properties. It is mainly recovered from residues and wastes in the production of other metals. The exploitation of the ores and wastes could contaminate water and soil creating environmental problems. This paper discusses recent developments and tendencies in scandium separation, purification and preconcentration from different wastes, residues, environmental samples as well as in the production of radiopharmaceuticals for nuclear medicine, both in the laboratory and on the industrial scale. The period reviewed here mainly includes publications that have appeared, since 2010.     

Specific Features of Distribution and Relaxation of Elastic Stresses in Homoepitaxial CVD Films of Germanium and Diamond

Crystallography Reports - The real structures of epitaxial CVD films of germanium and diamond have been comparatively analyzed. The influence of the specific features of elastic-stress distribution...     

Energetic structure–property relationships in thermochemistry of halogenosubstituted benzoic acids

Journal of Thermal Analysis and Calorimetry - Experimental thermodynamic properties of halogenosubstituted benzoic acids have been evaluated with the help of complementary in silico methods. The...     

Copper(II) complexes with pyridoxal dithiocarbazate and thiosemicarbazone ligands: crystal structure,spectroscopic analysis and cytotoxic activity

Transition Metal Chemistry - The present study reports the synthesis and crystal structures of Cu(II) complexes with pyridoxal S-allyldithiocarbazate (H2L1) and pyridoxal thiosemicarbazones...     

A New Approach for the Synthesis of Miktoarm Star Polymers Through a Combination of Thiol–Epoxy “Click” Chemistry and ATRP/Ring‐Opening Polymerization Techniques

A new approach was developed for synthesis of certain A₃B₃‐type of double hydrophilic or amphiphilic miktoarm star polymers using a combination of “grafting onto” and “grafting from” methods. To achieve the synthesis of desired miktoarm star polymers, acetyl protected poly(ethylene glycol) (PEG) thiols (M_n = 550 and 2000 g mol^?1) were utilized to generate A₃‐type of homoarm star polymers through an in situ protective group removal and a subsequent thiol–epoxy “click” reaction with a tris‐epoxide core viz. 1,1,1‐tris(4‐hydroxyphenyl)ethane triglycidyl ether. The secondary hydroxyl groups generated adjacent to the core upon the thiol–epoxy reaction were esterified with α‐bromoisobutyryl bromide to install atom transfer radical polymerization (ATRP) initiating sites. ATRP of N‐isopropylacrylamide (NIPAM) using the three‐arm star PEG polymer fitted with ATRP initiating sites adjacent to the core afforded A₃B₃‐type of double hydrophilic (PEG)₃[poly(N‐isopropylacrylamide)] (PNIPAM)₃ miktoarm star polymers. Furthermore, the generated hydroxyl groups were directly used as initiator for ring‐opening polymerization of ε‐caprolactone to prepare A₃B₃‐type of amphiphilic (PEG)₃[poly(ε‐caprolactone)]₃ miktoarm star polymers. The double hydrophilic (PEG)₃(PNIPAM)₃ miktoarm star polymers showed lower critical solution temperature around 34 °C. The preliminary transmission electron microscopy analysis indicated formation of self‐assembly of (PEG)₃(PNIPAM)₃ miktoarm star polymer in aqueous solution. © 2018 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2019 , 57, 146–156     

The 6j-Symbols for the SL(2, ℂ) Group

Theoretical and Mathematical Physics - We study 6j-symbols or Racah coefficients for the tensor products of infinite-dimensional unitary principal series representations of the group SL(2,...     

Quantum Mechanical Equivalence of the Metrics of a Centrally Symmetric Gravitational Field

Theoretical and Mathematical Physics - We analyze the quantum mechanical equivalence of the metrics of a centrally symmetric uncharged gravitational field. We consider the static Schwarzschild...     

Non‐self‐adjoint singular second‐order dynamic operators on time scale

In this study, maximal dissipative second‐order dynamic operators on semi‐infinite time scale are studied in the Hilbert space , that the extensions of a minimal symmetric operator in limit‐point case. We construct a self‐adjoint dilation of the dissipative operator together with its incoming and outgoing spectral representations so that we can determine the scattering function of the dilation as stated in the scheme of Lax‐Phillips. Moreover, we construct a functional model of the dissipative operator and identify its characteristic function in terms of the Weyl‐Titchmarsh function of a self‐adjoint second‐order dynamic operator. Finally, we prove the theorems on completeness of the system of root functions of the dissipative and accumulative dynamic operators.     

Poisson discretizations of Wiener functionals and Malliavin operators with Wasserstein estimates

This article proposes a global, chaos-based procedure for the discretization of functionals of Brownian motion into functionals of a Poisson process with intensity $\lambda >0$. Under this discretization we study the weak convergence, as the intensity of the underlying Poisson process goes to infinity, of Poisson functionals and their corresponding Malliavin-type derivatives to their Wiener counterparts. In addition, we derive a convergence rate of $O\left({\lambda }^{?1∕4}\right)$ for the Poisson discretization of Wiener functionals by combining the multivariate Chen–Stein method with the Malliavin calculus. Our proposed sufficient condition for establishing the mentioned convergence rate involves the kernel functions in the Wiener chaos, yet we provide examples, especially the discretization of some common path dependent Wiener functionals, to which our results apply without committing the explicit computations of such kernels. To the best our knowledge, these are the first results in the literature on the universal convergence rate of a global discretization of general Wiener functionals.